Axar Patel struck early to remove the openers after England chose to bat.
Siraj dismissed Root as England slipped to 30 for 3.
Stokes and Bairstow steadied England and took the side to 74 for 3 at lunch.
Siraj dismissed Bairstow in the fourth over of the second session.
Stokes fell for 55 as England went to Tea at 144 for 5.
Ashwin dismissed Pope early in the final session.
Axar picked four while Ashwin got three wickets as England folded for 205.
Anderson dismissed Gill in the very first over as India ended the day on 24 for 1.